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Visual chiral recognition of 1,1′-binaphthol through enantioselective collapse of gel based on an amphiphilic

Xuhong Zhang, Haimiao Li, Xin Zhang, Meng An, Weiwei Fang, Haitao Yu

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 231-237 doi: 10.1007/s11705-017-1633-3

摘要： A novel gelator that contained both Schiff base and L-lysine moieties was synthesized and its gelation behavior was tested. This gelator can form gels in various organic solvents. The resulting gel can be applied as a fascinating platform for visual recognition of enantiomeric 1-(2-hydroxynaphthalen-1-yl)naphthalen-2-ol (BINOL) through selective gel collapse. In addition, the mechanism for the reaction of the gel with chiral BINOL was investigated by scanning electron microscope and H nuclear magnetic resonance.

关键词： gelator     Schiff base     chiral recognition     gel formation     gel collapse    

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Microstructural and photocatalytic characterization of cement-paste sol-gel synthesized titanium dioxide

Elena CERRO-PRADA,Miguel MANSO,Vicente TORRES,Jesús SORIANO

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 189-197 doi: 10.1007/s11709-015-0326-6

摘要： A route for the in paste synthesis of TiO loaded cement is described. TiO sols are blended with fresh cement paste as an alternative process to add photocatalytic functionality to cement. The modification of cement paste structure after the addition of TiO sols is analyzed by XRD, SEM and TGA. As a particular microstructural feature, TiO containing calcium silicate hydrate (C-H-S) particles are identified as networking centers of a C-S-H gel fiber matrix. The increase of the TiO sol concentration induces a decrease of pore size and an increase in the specific surface area in the cement composites. The photocatalytic activity of the TiO /cement system is evaluated from the degradation of Methylene Blue (MB) under UV irradiation, monitored through the absorbance at 665 nm. The results show that, although TiO phases reveal no long range order structure, the cement paste exothermal treatment in presence of hydrate products and alkaline conditions leads to a photocatalytic composite. Such new cement matrix may be twofold advantageous since it additionally promotes the formation of C-S-H gel, main determinant of cement mechanical properties.

关键词： cement composites     photocatalytic TiO2     sol-gel     C-S-H gel     microstructure    

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表面张力作用下柱形胶体的弹性失稳

黄殿武,乔玲,汪时机

《中国工程科学》 2007年 第9卷 第4期   页码 50-54

摘要：

采用弹性理论研究了圆柱形胶体在表面张力作用下的弹性失稳问题；利用能量泛函变分的方法导出 了发生弹性失稳的非经典边界条件，得到了失稳的判据方程。分析判据方程发现，弹性失稳与圆柱体的半径、 内禀尺度和失稳波长相关。

关键词： 柱形胶体     弹性失稳     内禀尺度     表面效应    

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溶胶-凝胶原位生长制备超疏水木材

梁金,吴义强,刘明

《中国工程科学》 2014年 第16卷 第4期   页码 87-91

摘要：

采用溶胶-凝胶原位生长的方法制备超疏水木材，在木材表面形成一层纳米结构超疏水薄膜，水滴在木材表面接触角达到150.6°。采用X射线衍射仪（XRD）、扫描电子显微镜（SEM）、傅立叶变换红外光谱仪（FTIR）分别对超疏水木材样品的物相组成、表面形貌及表面化学官能团进行检测，分析表明木材的超疏水性是表面纳米级突起粗糙结构和乙烯基疏水基团共同作用的结果。

关键词： 木材     超疏水     溶胶-凝胶     纳米    

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A small-scale silica gel-water adsorption system for domestic air conditioning and water heating by the

Y. YU, Q. W. PAN, L. W. WANG

《能源前沿（英文）》 2020年 第14卷 第2期   页码 328-336 doi: 10.1007/s11708-019-0623-1

摘要： A small-scale silica gel-water adsorption system with modular adsorber, which utilizes solar energy to achieve the cogeneration of domestic air conditioning and water heating effect, is proposed and investigated in this paper. A heat recovery process between two adsorbers and a mass recovery process between two evaporators are adopted to improve the overall cooling and heating performance. First, the adsorption system is tested under different modes (different mass recovery, heat recovery, and cogeneration time) to determine the optimal operating conditions. Then, the cogeneration performance of domestic cooling and water heating effect is studied at different heat transfer fluid temperatures. The results show that the optimal time for cogeneration, mass recovery, and heat recovery are 600 s, 40 s, and 40 s, respectively. When the inlet temperature of hot water is around 85°C, the largest cooling power and heating power are 8.25 kW and 21.94 kW, respectively. Under the condition of cooling water temperature of 35°C, the obtained maximum COP , COP , and SCP of the system are 0.59, 1.39, and 184.5 W/kg, respectively.

关键词： silica gel-water     heat and mass recovery     solar energy     domestic cooling and heating    

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Time-varying formation tracking for uncertain second-order nonlinearmulti-agent systems

Mao-peng RAN, Li-hua XIE, Jun-cheng LI

《信息与电子工程前沿（英文）》 2019年 第20卷 第1期   页码 76-87 doi: 10.1631/FITEE.1800557

摘要：

Our study is concerned with the time-varying formation tracking problem for second-order multi-agent systems that are subject to unknown nonlinear dynamics and external disturbance, and the states of the followers form a predefined time-varying formation while tracking the state of the leader. The total uncertainty lumps the unknown nonlinear dynamics and the external disturbance, and is regarded as an extended state of the agent. To estimate the total uncertainty, we design an extended state observer (ESO). Then we propose a novel ESO based time-varying formation tracking protocol. It is proved that, under the proposed protocol, the ESO estimation error and the time-varying formation tracking error can be made arbitrarily small. An application to the target enclosing problem for multiple unmanned aerial vehicles (UAVs) verifies the effectiveness and superiority of the proposed approach.

关键词： Multi-agent system     Time-varying formation     Formation tracking     Nonlinear dynamics     Extended state observer (ESO)    

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Experimental research on dynamic operating characteristics of a novel silica gel-water adsorption chiller

WANG Dechang, WU Jingyi, WANG Ruzhu, DOU Weidong

《能源前沿（英文）》 2007年 第1卷 第3期   页码 347-351 doi: 10.1007/s11708-007-0052-4

摘要： A novel silica gel-water adsorption chiller consisting of two adsorption/desorption chambers and an evaporator with one heat-pipe working chamber is experimentally studied. The dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are obtained. The experimental results show that the dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are satisfactory and that the cycle is a novel and effective adsorption cycle. A mass recovery process increases the cyclic adsorption capacity of the system and improves adaptability of the chiller to a low-grade heat source. In addition, the experiment indicates that this novel chiller is highly suitable for an air conditioning system with a low dehumidification requirement or a system with a large cycle flowrate and an industrial cooling water system.

关键词： satisfactory     suitable     recovery     adsorption capacity     thermodynamic    

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3D finite element prediction of chip flow, burr formation, and cutting forces in micro end-milling of

A. DAVOUDINEJAD, P. PARENTI, M. ANNONI

《机械工程前沿（英文）》 2017年 第12卷 第2期   页码 203-214 doi: 10.1007/s11465-017-0421-6

摘要：

Predictive models for machining operations have been significantly improved through numerous methods in recent decades. This study proposed a 3D finite element modeling (3D FEM) approach for the micro end-milling of Al6061-T6. Finite element (FE) simulations were performed under different cutting conditions to obtain realistic numerical predictions of chip flow, burr formation, and cutting forces. FE modeling displayed notable advantages, such as capability to easily handle any type of tool geometry and any side effect on chip formation, including thermal aspect and material property changes. The proposed 3D FE model considers the effects of mill helix angle and cutting edge radius on the chip. The prediction capability of the FE model was validated by comparing numerical model and experimental test results. Burr dimension trends were correlated with force profile shapes. However, the FE predictions overestimated the real force magnitude. This overestimation indicates that the model requires further development.

关键词： 3D finite element modeling     micro end-milling     cutting force     chip formation     burr formation    

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Mechanistic insight into the biofilm formation and process performance of a passive aeration ditch (PAD

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1494-3

摘要：

• A Passive Aeration Ditch was developed to treat decentralized wastewater.

关键词： Decentralized wastewater     Passive aeration ditch     Biofilm formation     C/N ratio     Salinity     Model simulation    

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Is atmospheric oxidation capacity better in indicating tropospheric O formation?

《环境科学与工程前沿（英文）》 2022年 第16卷 第5期 doi: 10.1007/s11783-022-1544-5

摘要：

● This study summarizes and evaluates different approaches that indicate O3 formation.

关键词： O3     AOC     O3 formation regime    

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WO3 nanomaterials synthesized via a sol-gel method and calcination for use as a CO gas sensor

Diah SUSANTI,A.A. Gede Pradnyana DIPUTRA,Lucky TANANTA,Hariyati PURWANINGSIH,George Endri KUSUMA,Chenhao WANG,Shaoju SHIH,Yingsheng HUANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 179-187 doi: 10.1007/s11705-014-1431-0

摘要： Carbon monoxide is a poisonous and hazardous gas and sensitive sensor devices are needed to prevent humans from being poisoned by this gas. A CO gas sensor has been prepared from WO synthesized by a sol-gel method. The sensor chip was prepared by a spin-coating technique which deposited a thin film of WO on an alumina substrate. The chip samples were then calcined at 300, 400, 500 or 600 °C for 1 h. The sensitivities of the different sensor chips for CO gas were determined by comparing the changes in electrical resistance in the absence and presence of 50 ppm of CO gas at 200 °C. The WO calcined at 500 °C had the highest sensitivity. The sensitivity of this sensor was also measured at CO concentrations of 100 ppm and 200 ppm and at operating temperatures of 30 and 100 °C. Thermogravimetric analysis of the WO calcined at 500 °C indicated that this sample had the highest gas adsorption capacity. This preliminary research has shown that WO can serve as a CO gas sensor and that is should be further explored and developed.

关键词： WO3 nanomaterial     sol-gel     calcinations     CO gas sensor     sensitivity    

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Formation mechanism and modeling of surface waviness in incremental sheet forming

《机械工程前沿（英文）》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0679-1

摘要： Improving and controlling surface quality has always been a challenge for incremental sheet forming (ISF), whereas the generation mechanism of waviness surface is still unknown, which impedes the widely application of ISF in the industrial field. In this paper, the formation mechanism and the prediction of waviness are both investigated through experiments, numerical simulation, and theoretical analysis. Based on a verified finite element model, the waviness topography is predicted numerically for the first time, and its generation is attributed to the residual bending deformation through deformation history analysis. For more efficient engineering application, a theoretical model for waviness height is proposed based on the generation mechanism, using a modified strain function considering deformation modes. This work is favorable for the perfection of formation mechanism and control of surface quality in ISF.

关键词： surface waviness     incremental sheet forming     numerical simulation     formation mechanism     deformation history    

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New insights into the formation of ammonium nitrate from a physical and chemical level perspective

《环境科学与工程前沿（英文）》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1737-6

摘要：

● Factor analysis of ammonium nitrate formation based on thermodynamic theory.

关键词： Ammonium nitrate formation     Thermodynamic theory     Aerosol liquid water content     Source apportionment    

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Mercury removal and recovery by immobilized

Meifang CHIEN, Ryo NAKAHATA, Tetsuya ONO, Keisuke MIYAUCHI, Ginro ENDO

《化学科学与工程前沿（英文）》 2012年 第6卷 第2期   页码 192-197 doi: 10.1007/s11705-012-1284-3

摘要： From several mercury removing microorganisms, we selected MB1, which is non-pathogenic, broad-spectrum mercury resistant, mercuric ion reducing, heat tolerant, and spore-forming, as a useful bacterium for bioremediation of mercury pollution. In this study, mercury removal performance of the immobilized MB1 was investigated to develop safe, efficient and stable catalytic bio-agent for mercury bioremediation. The results showed that the alginate gel immobilized MB1 cells efficiently removed 80% of mercury from the solution containing 10 mg/L mercuric chloride within 24 h. These cells still had high activity of mercury removal even after mercuric ion loading was repeated for nine times. The analysis of mercury contents of the alginate beads with and without immobilized MB1 suggested that a large portion of reduced metallic mercury was trapped in the gel beads. It was concluded that the alginate gel immobilized MB1 cells have potential to remove and recover mercury from mercury-containing water.

关键词： mercury removal     immobilized bacteria     alginate gel     bioremediation    

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High-precision standard enthalpy of formation for polycyclic aromatic hydrocarbons predicting from general

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1743-1750 doi: 10.1007/s11705-022-2184-9

摘要： The standard enthalpy of formation is an important predictor of the reaction heat of a chemical reaction. In this work, a high-precision method was developed to calculate accurate standard enthalpies of formation for polycyclic aromatic hydrocarbons based on the general connectivity based hierarchy (CBH) with the discrete correction of atomization energy. Through a comparison with available experimental findings and other high-precision computational results, it was found that the present method can give a good description of enthalpy of formation for polycyclic aromatic hydrocarbons. Since CBH schemes can broaden the scope of application, this method can be used to investigate the energetic properties of larger polycyclic aromatic hydrocarbons to achieve a high-precision calculation at the CCSD(T)/CBS level. In addition, the energetic properties of CBH fragments can be accurately calculated and integrated into a database for future use, which will increase computational efficiency. We hope this work can give new insights into the energetic properties of larger systems.

关键词： standard enthalpy of formation     polycyclic aromatic hydrocarbons     connectivity based hierarchy     high-precision calculation    

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标题 作者 时间 类型 操作

Visual chiral recognition of 1,1′-binaphthol through enantioselective collapse of gel based on an amphiphilic

Xuhong Zhang, Haimiao Li, Xin Zhang, Meng An, Weiwei Fang, Haitao Yu

期刊论文

Microstructural and photocatalytic characterization of cement-paste sol-gel synthesized titanium dioxide

Elena CERRO-PRADA,Miguel MANSO,Vicente TORRES,Jesús SORIANO

期刊论文

表面张力作用下柱形胶体的弹性失稳

黄殿武,乔玲,汪时机

期刊论文

溶胶-凝胶原位生长制备超疏水木材

梁金,吴义强,刘明

期刊论文

A small-scale silica gel-water adsorption system for domestic air conditioning and water heating by the

Y. YU, Q. W. PAN, L. W. WANG

期刊论文

Time-varying formation tracking for uncertain second-order nonlinearmulti-agent systems

Mao-peng RAN, Li-hua XIE, Jun-cheng LI

期刊论文

Experimental research on dynamic operating characteristics of a novel silica gel-water adsorption chiller

WANG Dechang, WU Jingyi, WANG Ruzhu, DOU Weidong

期刊论文

3D finite element prediction of chip flow, burr formation, and cutting forces in micro end-milling of

A. DAVOUDINEJAD, P. PARENTI, M. ANNONI

期刊论文

Mechanistic insight into the biofilm formation and process performance of a passive aeration ditch (PAD

期刊论文

Is atmospheric oxidation capacity better in indicating tropospheric O formation?

期刊论文

WO3 nanomaterials synthesized via a sol-gel method and calcination for use as a CO gas sensor

Diah SUSANTI,A.A. Gede Pradnyana DIPUTRA,Lucky TANANTA,Hariyati PURWANINGSIH,George Endri KUSUMA,Chenhao WANG,Shaoju SHIH,Yingsheng HUANG

期刊论文

Formation mechanism and modeling of surface waviness in incremental sheet forming

期刊论文

New insights into the formation of ammonium nitrate from a physical and chemical level perspective

期刊论文

Mercury removal and recovery by immobilized

Meifang CHIEN, Ryo NAKAHATA, Tetsuya ONO, Keisuke MIYAUCHI, Ginro ENDO

期刊论文

High-precision standard enthalpy of formation for polycyclic aromatic hydrocarbons predicting from general

期刊论文